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CEE 543, Autumn 2007
Aquatic Chemistry

Mark Benjamin                                        Class Sessions: MWF 10:30 More 225; T 1:30 Johnson 022

335 More Hall                                          206-543-7645 (v); 206-685-9185 (f)

 markbenj@u.washington.edu                    Office Hrs: TTh 2:30-3:20

http://faculty.washington.edu/markbenj/CEE543

Required Text: Water Chemistry, Benjamin (McGraw-Hill, 2002)  Note: See Errata List

Reference Texts: A Problem-Solving Approach to Aquatic Chemistry, Jensen (Wiley, 2003)

Aquatic Chemistry, Stumm and Morgan (Wiley, 1996)

Water Chemistry, Snoeyink and Jenkins (Wiley, 1980)

Aqueous Environmental Geochemistry, Langmuir (Prentice-Hall, 1997)

Principles & Applications of Aquatic Chemistry, Morel and Hering (Wiley, 1993)

Session

Date

Topics

Reading

1

9/26

Introduction; Perspectives on Chemical Equilibrium;
Concentration Scales

1-19

2

9/28

Concentration and Activity; Activity Coefficients in Solution

19-51

3,4

10/1,2

Thermodynamic Fundamentals

60-62, 75-96

5

10/3

Thermodynamic Interpretation of Equilibrium

96-127

6

10/5

Acidity Constants, Acid Strength

131-150

7,8

10/8,9

Graphical Representation of Acid/Base Equilibria

150-161

9

10/10

Mass and Charge Balances,
Numerical Solutions of Acid/Base Problems

161-185

10

10/12

Graphical Solutions to Acid/Base Problems, Proton Condition

188-230

11,12

10/15,16

Titrations

 

13

10/17

Alkalinity

237-257

14

10/19

Buffers

257-276

15,16

10/22,23

Software for Chemical Equilibrium Problems; Mineql+ usage notes, Part1

276-288

17

10/26

Computer session 1a: Acids and Bases

 

18

10/29

Computer session 1b: Fixed Activity Species

 

19,20

10/30

Gas/Liquid Equilibrium

322-357

21

10/31

Gas/Liquid Equilibrium in Mineql+; Mineql+ usage notes, Part2

 

22

11/2

Computer session 2: Gases

 

23

11/5

Metals in Solution: Coordination Chemistry and Speciation

362-394

24,25

11/6,7

Precipitation of Metal Hydroxides

394-404

26

11/9

Precipitation of Metal Hydroxides  

 

11/12

VETERANS’ DAY HOLIDAY

 

27

11/13

Computer session 3: Metals in Solution  

28

11/14

Precipitation of Metal Carbonates and Phosphates

404-421

29

11/16

Computer session 4: Equilibrium with Known Solids

 

30,31

11/19,20

Systems with Potential Precipitation

421-433

23

11/21

NO CLASS

 

 24

11/23

THANKSGIVING HOLIDAY

 

32

11/26,27

Computer session 5: Systems with Potential Precipitation  

33

11/28

The Phase Rule; Predominance Area Diagrams with Solids

433-453

34

11/30

Oxidation-Reduction Reactions; Redox Reactions and Energy

464-496

35,36

12/3,4

Redox Speciation; Redox Titrations and Buffering

496-525

37

12/5

Computer session 6: Redox Equilibrium 525-545

38

12/7

Catch up, Review, Summarize  

 

12/10

FINAL EXAM, 8:30-10:20