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Surface Reactions in High Electric Fields

Field Ionization of Water

Kinetics and Mechanism of Methanol Electrocatalysis

Pulsed Injection Flow Cell for Methanol Electrocatalysis

Nanocatalysis

 

 

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Kinetics and Mechanism of Methanol Electrocatalysis


UW Center for Nanotechnology)


We examine the kinetics and mechanism of methanol oxidation on platinum and modified-platinum electrodes.  Our goal is to obtain accurate kinetics data and measure partial oxidation products produced in the reaction.  These reactions are done at 20-100 °C.  We have developed a silicon-based micro-reactor that enables study of single crystal platinum, polycrystalline platinum, and real platinum catalysts.  We are also building a DEMS (differential electrochemical mass spectrometry) system for measurement of partial oxidation products.  A PowerPoint poster detailing the electrochemical microreactors is available through the link below.  Graduate students Nallakkan Arvindan (Arvind) and Laura Roen are working on this project.
Electrochemical Microreactor Poster (1 MB)

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 Last Updated:
05/08/03 v 2.0.0
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