CHEM 461- PHYSICAL CHEMISTRY LABORATORY
Spring 2001
1:305:20 P.M. Sec. ZA/ZB on M,W; Sec. ZC/ZD on Tu,Th; Bagley 333
Instructor:
Sarah Keller, Bagley 219, 543-9613, Office hours by appointment
e-mail:
slkeller@chem.washington.eduTeaching Assistants:
Geoffrey Glass M/TU
fegforey@yahoo.comSteve Parker CHB 028, 616-4270 M/TU
parkersc@u.washington.eduKristopher Schumacher Benson 343, W/TH kristop@u.washington.edu
Paul Wallace BAG 054, 543-3297 W/TH
paulmwallace@hotmail.comLaboratory Supervisor:
Doug Schaaf Bagley 333C
Books on Reserve in the Chemistry Library (if you need them):
Levine, Physical Chemistry, 3rd Edition
Daniels et al., Experimental Physical Chemistry
Bevington, Data Reduction and Analysis for the Physical Sciences
Taylor, An Introduction to Error Analysis
Strunk and White, Elements of Style
Prerequisites:
A. Chem 161 or Phys 132 or a higher level laboratory
B. Chem 455, 456 (or Chem E 326), 457 (which may be taken concurrently)
or Chem 452, 455.
Statistics Worksheets:
On the first day of class you will be given a statistics worksheet. It must be completed and returned by the third day of class. Many students find that the easiest way to complete the statistics worksheet is to use a statistics introduction which can be purchased in the stockroom. The text by Taylor on error analysis is an excellent resource for almost any query you may have in the future many scientists swear by this book and it is especially written as a clear intro for students. I highly recommend that you invest in Taylors book.
You must do all of the work on the statistics worksheet by hand, not by using a program such as Excel! Using a program to plot data is o.k., but using it to generate values for statistics and errors is not. If you want to use a program, it has to be one you have written yourself and you must hand in documentation of the program or spreadsheet functions you use. The point is that you need to learn about statistics and the propagation of errors for yourself. This is so important that if you make a mistake on the worksheet, it will be handed back until you get it right. Your grade will be based on how many times it is handed back.
Chem-461 Handout
Each lab has a handout which can be purchased for $1.00 at the Undergraduate Stockroom, Bagley 271. It should be purchased at least one week before the preliminary quiz for each lab.
Preliminary Quizzes:
A preliminary quiz is held during the first hour of lab during the first day of each two-week experiment. To pass the preliminary quiz, you need to have (1) carefully read and understood the Chem 461 "handout" for that experiment, (2) reviewed the suggested sections in your p-chem text and perhaps some additional reference material, and (3) prepared yourself to answer the questions in the "handout." (These questions are frequently asked on the preliminary exam.) In other words, to pass the preliminary exam, you must have thought carefully about the experiment, and relearned the theory required to understand the experiment. You will not be allowed to use the "handouts" during the preliminary quizzes. You may, however, write a page of notes based on the handouts which you can use on the quizzes. An appropriate place for these notes is in your lab notebook. You must turn in the quiz before you can start the lab.
It may seem as if the quizzes are yet another time-consuming hurdle, but they are actually there to save you time. Weve found that putting some time into thinking at the beginning of an experiment can sometimes cut an entire day off of the time to complete a lab! Many labs will only take you 3 sessions (rather than 4) to complete.
Final Exam:
There will be a final exam which covers only the specific experiments you performed. It counts for as many points as one lab report, so it is a major part of your grade. This means you must master the material to pass the class. The point is to test your familiarity with the theoretical concepts and instrumentation used in the experiments. Also, such end-of-quarter reviews have proven to greatly help students to see the "big picture" and to store important course concepts in their long-term memories. You will be given your graded reports back on the last week of classes to study for the final exam. These must, however, be returned on the final exam day, or you will not be permitted to take the final exam. You will be allowed to have two 8-1/2 x 11" pages of notes, written on both sides, but no other books, notes, or reports. You may be given some of your own data to analyze as part of the exam, particularly in the questions relating to experiments from groups I and IV (see below).
Experiments:
Group I (Lab Report = 80 points)
#3 - Bomb Calorimetry Paul Wallace
#4 - Heat of Solution Geoffrey Glass
Group II (Lab Report = 80 points)
#6 - Vapor Pressure of a Pure Substance Kristopher Schumacher
#9 - Liquid/Vapor Equilibrium in Binary Solutions Kristopher Schumacher
Group III (Lab Report = 80 points)
#1 - Kinetics by UV/VIS Spectroscopy Steve Parker
#88 - Luminescence Dynamics Steve Parker
Group IV (Lab Report = 80 points)
#42 - HCl/DCl Infrared Spectroscopy Paul Wallace
#44 - Viscosity and Polymers Geoffrey Glass
The experiments and their associated "Lab Reports" constitute the essence of this laboratory course. You will be required to perform one experiment from each of the four groups above (unless you are taking this class for 2 credits, in which case you must only perform three such experiments). You will be given four full lab days to complete each experiment. Your active and safe performance in the lab will be graded jointly by the professor, lab supervisor, and TAs and summed into a lab evaluation grade (40 points).
The four experiments that each student must perform will be posted in Bagley 333 on the first day of lab. Dont forget, you have to get your handout for the first experiment by that day too, so you can read it before the next lab meeting. Your first preliminary quiz will be at that meeting, on Apr. 2 (Sec. ZA/ZB) or Apr. 3 (Sec. ZC/ZD).
Lab Safety:
Consider your own safety as well as that of others while you work in the lab and dispose of chemicals. Note the safety precautions and waste handling procedures in the handouts. It is at this stage in your life that you must start making moral decisions about procedures that require more work for you, but will ensure the continued safe and enjoyable life on this planet for future generations. Before pouring something down the drain, consider whether anyone you care about likes to eat fish. Goggles are required in the lab at all times! A lab coat is a good idea, but not required.
Lab Reports (General)
Reports are due at the start of lab on the third day of your next experiment. Make sure to give your report to a TA and watch him/her sign in the record book and write the time and date your report was received. This will protect you if your report is misplaced. If reports are more than 15 minutes late, they will be assessed a 20 point penalty. If they are more than one week late, no credit will be given.
Lab reports should be graded within one week after they are submitted. Please ask the TA to show you your graded report one week after you have turned it in, so you can learn what is expected on the reports and fix conceptual problems. These will serve as valuable feedback in preparing your next report. The reports, however, cannot be removed from the lab. If your reports are not graded in time, please inform the instructor as soon as possible to the problem can be rectified. Any questions regarding grading policy should be directed to the instructor, not the TA.
Lab Reports (Specific)
I. Introduction = 11 points (up to 4 pages)
Describe what the experiments are to achieve. Show that you know the physical and chemical concepts behind the measurements and the apparatus, and introduce any theoretical calculations which will be necessary for data analysis in Section III. Show youve read the background material by correctly and heavily referencing it!
II. Experiment = 3 points (1 page)
Simply reference the handout, noting differences in actual procedure used and why you changed the procedure.
III. Results and Discussion = 60 points (up to 10 pages)
IV. Conclusion = 5 points (1 page)
Summarize in less than 1 page the experiments, results, and conclusions. (Like an abstract.)
V. Literature References = 1 point (1 page)
VI. Appendices = required for III (Points off if units and unit analysis are not clear!)
In addition, there are "Questions" sections in each lab handout. If these questions have not been answered in Sections I, III, or IV of your report, you must cover these in a separate section at the end of your report. If they have been answered in your report, please highlight each answer in the text with a large red "Q1" or "Q2", etc., in the left margin.
Finally, TAs tend to give high grades and have a warm place in their hearts for students who have good penmanship and use clear, concise English (quantity ‚ quality). Do not feel obliged to write the maximum number of pages of lab report.
Lab Notebooks:
You must keep a lab notebook (available in the bookstore) which has carbon-copy pages behind each page. You should use this notebook to:
1) Take notes when reading the handout in preparation for each experiment.
2) Answer questions which occur in the handouts.
3) Outline your plans for each experiment before you enter the lab.
4) Neatly and carefully record data in ink as you acquire results in the lab. You should also put your name on each page you use, and date it.
At the end of each period, you must turn in the carbon-copy pages to the TA. As a point of note: careful versus sloppy record-keeping of lab notebooks has made the crucial difference in many billions of dollars in patent lawsuit decisions in recent years.
Course Grading:
Statistics Worksheets 60 points
Four experiments
Preliminary Quiz 20 points each
Lab Report 80 points each
Total 100 points each x 4 400 points
Lab Evaluation 40 points
Final Exam 100 points
TOTAL 600 points
Be forewarned: TAs grade differently. Some are easy graders, some are hard. To make it fair for everyone, all the scores given by one TA will be curved together so that each TAs grades have the same average. This means that if you get an easy TA, your score may be curved down! You have been forewarned.
If you are taking this class for only two credits, appropriate factors will be used to scale the total number of points. You will be graded on a curve based on this 600 point total, such that the class average is ‰ 2.8. Usually, only a few people make 4.0s. Anyone scoring less than 60% of the points earned by the top 10% of the class will make 0.0 for the course grade.
SCHEDULE: (all in Bagley 333).
Mar. 26, 27: |
Pick up class handouts. Statistics worksheet handed out. Lecture on course objectives/logistics and safety issues. Check into lab desks. |
Mar. 28, 29: |
Lab test on stoichiometric concepts and proficiency in use of volumetric glassware. Record your lab experiment schedule; get first experiment's handout. Be sure to carefully read the handout for your first experiment before the next class meeting to prepare for the preliminary exam. |
Apr. 212: |
First Experiment. |
LectureApr. 11, 12 on format for lab reports (Stat worksheets due Apr. 2,3 for first try, Apr 9, 10 for second try; lab report due Apr. 23, 24) |
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Apr. 1626: |
Second Experiment. |
(Report due May 7, 8) |
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Apr. 30May 10: |
Third Experiment. |
(Report due May 21, 22) |
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May 1424: |
Fourth Experiment. |
(Report due May 30, 31) |
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May 28, 29: |
Lab closed. |
May 30, 31: |
Last lab report due; lab check-out. |
Jun. 6 (Wed.): |
Final exam. All sections, 12:30-2:20 P.M. (Room will be posted in the lab 2 weeks before the final.) |
Note: Please check your full final exam schedule to make sure you have no other exams which conflict with this time. If you do have a conflict, you must tell Prof. Keller before April 4. |