Heat generation at the walls

Question: Without heat generation at the walls, the temperature remains constant throughout the reactor. By adding heat generation, will the final ammonia concentration be higher, lower, or no effect?

Higher

Lower

No effect
 
 

Correct!!!

The heat generation will increase the temperature in the reactor, but not significantly, as shown below.

The contour plots look very similar for all conditions; only the maximum temperature changes.
 
 

Rate of heat generation 0 0.1227 1.227 12.27
Maximum temperature 673 673.07 673.7 679.97

Graph 4.31      Graph 4.32      Graph 4.33

NOTE: There is no contour plot for heat generation=0 because the temperature is constant throughout the reactor.

Because the temperature in the reactor is not significantly affected by the heat generation, the minimum ammonia concentration is not significantly affected either, as shown in the contour plots below (heat generation rate increases from left to right).
 
 

Rate of heat generation 0 0.1227 1.227 12.27
Minimum ammonia concentration 0.24312 0.2459 0.23881 0.25836

Graph 4.34       Graph 4.35        Graph 4.36      Graph 4.37

To confirm that the slight increase in temperature to 679.97, for the highest heat generation rate, does not significantly affect the final ammonia concentration, the model was re-run with no heat generation but an inlet temperature of T=680. The ammonia concentration plot, shown below, indicates that the minimum ammonia concentration is 0.25527, which is similar to the value obtained for the heat generation=12.27 run.

Graph 4.38

 


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